Xylene Sulphonic Acid – Product identifier 1 Identification 2 Xylene Sulphonic Acid – Hazard(s) identification · Classification of the substance or mixture May be corrosive to the eyes. May be corrosive to the skin. Can cause severe respiratory irritation. May be harmful if swallowed · Label elements · GHS label elements The product is classified and labeled according to the Globally Harmonized System (GHS). · Hazard pictograms · Signal word Warning · Hazard statements · May be corrosive to the eyes. · May be corrosive to the skin. · Can cause severe respiratory irritation. · May be harmful if swallowed · Precautionary statements Wear protective gloves / protective clothing / eye protection / face protection. If swallowed: Call a poison center / doctor if you feel unwell. If on skin: Wash with plenty of water. Call a poison center / doctor if you feel unwell. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If exposed or concerned: Call a poison center / doctor · Classification system: · NFPA ratings (scale 0 – 4) · Other hazards · Results of PBT and vPvB assessment · PBT: Not applicable. · vPvB: Not applicable. 3 Xylene Sulphonic Acid – Composition/information on ingredients Chemical characterization: Mixtures Description: Mixture of the substances listed below with nonhazardous additions. Description of first aid measures General information: First aiders need to protect themselves. Show this material safety data sheet to the doctor in attendance. After inhalation: Fresh air. If symptoms persist call in physician. After skin contact: Rinse skin with water / shower. If irritation develops or persist take off immediately all contaminated clothing. After eye contact: Rinse out with plenty of water. Immediately call in ophthalmologist. After swallowing: Immediately consult a physician. Information for doctor: Most important symptoms and effects, both acute and delayed No further relevant information available. Indication of any immediate medical attention and special treatment needed No further relevant information available. Extinguishing media Suitable extinguishing agents: Water fog, Foam, Carbon Dioxide (CO2), Dry chemical powder. Special hazards arising from the substance or mixture Material is not flammable but if involved in a fire could give off toxic fumes such as Sulphur dioxide. Advice for firefighters: Stay in danger area only with self-contained breathing apparatus. Protective equipment: Mouth respiratory protective device. · Personal precautions, protective equipment and emergency procedures Avoid breathing (vapour, mist, spray). Mount respiratory protective device. Wear protective equipment. Keep unprotected persons away. · Substances: CAS: 25321-41-9 Xylene Sulphonic Acid ˃ 89 CAS: 7732-18-5 Water < 5 CAS: 7664-93-9 Sulfuric Acid < 4.5 CAS: 1330-20-7 Xylene < 0.5 4 First-aid measures 5 Fire-fighting measures 6 Xylene Sulphonic Acid – Accidental release measures Environmental precautions: Avoid release to the environment. Prevent any leakage or spillage if safe to do so. Methods and material for containment and cleaning up: Prevent entry into waterways, sewers, basement or confined space. Reference to other sections See Section 7 for information on safe handling. See Section 8 for information on personal protection equipment. See Section 13 for disposal information. Protective Action Criteria for Chemicals 7 Xylene Sulphonic Acid – Handling and storage Handling: Avoid skin and eye contact. Wash thoroughly after handling. Precautions for safe handling Avoid skin, eye and clothing contact. Wash hands thoroughly after handling. Ensure good ventilation/exhaustion at the workplace. Open and handle with care. Information about protection against explosions and fires: Keep ignition sources away – Do not smoke. Keep respiratory protective device available. Conditions for safe storage, including any incompatibilities Storage: Avoid mild steel storage. Avoid extremes of temperature (45℃). Keep container in a well-ventilated place. Requirements to be met by storerooms and receptacles: Store in a cool location. Information about storage in one common storage facility: Not required. Further information about storage conditions: Keep receptacle tightly sealed. Store in cool, dry conditions in well sealed receptacles. Specific end use(s) No further relevant information available. 8 Exposure controls/personal protection · Exposure controls · Personal protective equipment: · General protective and hygienic measures: Keep away from foodstuffs, beverages and feed. Immediately remove all soiled and contaminated clothing. Wash hands before breaks and at the end of work. Store protective clothing separately. Avoid contact with the eyes and skin. · Breathing equipment: In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use respiratory protective device that is independent of circulating air. · Protection of hands: The glove material has to be impermeable and resistant to the product/ the substance/ the preparation. Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the chemical mixture. Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation · Material of gloves The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the application. · Penetration time of glove material · The exact break through time has to be found out by the manufacturer of the protective gloves and has to be observed. · Eye protection: Wear chemical goggles or face shield. · Body protection: Protective work clothing 9 Physical and chemical properties · Information on basic physical and chemical properties · General Information · Appearance: Form: Liquid Color: Dark Brownish · Odor: Slight Hydrocarbon · Odor threshold: Not determined. · pH-value: < 1 · Change in condition Freezing point/Freezing range: Boiling point/Boiling range: -18 ℃ Not applicable. · Flash point: ˃ 94℃ · Flammability (solid, gaseous): Not applicable. · Molecular Weight: Not applicable. · Decomposition temperature: Not determined. · Ignition temperature: Not applicable. · Danger of explosion: Not applicable. · Vapor pressure: Not applicable. · Relative density · Vapor density · Evaporation rate 1.24 g/mᵌ Estimated heavier than air. Not determined. · Solubility in / Miscibility with Water: Not applicable. · Partition coefficient (n-octanol/water): Not determined. · Viscosity: Dynamic: Kinematic: Not determined. Not determined. · Other information No further relevant information available. 10 Stability and reactivity Reactivity No further information available. Chemical stability: Stable under normal conditions. Thermal decomposition / conditions to be avoided: No data available. Possibility of hazardous reactions Will not occur. Conditions to avoid Extremes of temperature. Incompatible materials: Strong oxidants and strong alkalis. Hazardous decomposition products: Sulphur oxides, sulphuric acid. 11 Toxicological information Information on toxicological effects Acute toxicity: Primary irritant effect: on the skin: Corrosive, skin burns. on the eye: Risk of persistent effects in the eye. Ingestion: May cause nausea. No toxic effect expected. Additional toxicological information: The product shows the following dangers according to internally approved calculation methods for preparations: Irritant to skin and serious eye damage. · IARC (International Agency for Research on Cancer) None of the ingredients is listed. · NTP (National Toxicology Program) None of the ingredients is listed. · OSHA-Ca (Occupational Safety & Health Administration) None of the ingredients is listed. 14 Transport information · UN-Number · DOT, IMDG, IATA UN2586 · UN proper shipping name · DOT · IMDG, IATA Alkyl, aryl sulphonic acid, Liquid with not more than 5% free Sulphuric Acid · Waste treatment methods No data available. · Uncleaned packagings: · Recommendation: Disposal must be made according to official regulations. · Recommended cleansing agent: Water, if necessary with cleansing agents. 13 Disposal considerations Toxicity: to fish, to daphnia and other aquatic invertebrates, to algae. Aquatic toxicity: No further relevant information available. Persistence and degradability No further relevant information available. Behavior in environmental systems: Bio accumulative potential No further relevant information available. Mobility in soil No further relevant information available. Additional ecological information: General notes: Do not allow product to reach drains. Results of PBT and vPvB assessment PBT: Not applicable. vPvB: Not applicable. Other adverse effects No further relevant information available. 12 Ecological information · Safety, health and environmental regulations/legislation specific for the substance or mixture No further relevant information available. (Contd. on page 10) 15 Regulatory information · Transport hazard class(es) · DOT OClass 8 · IMDG, IATA .Class 8 · Packing group IMDG, IATA III · Environmental hazards: Yes · Marine pollutant: No · Special precautions for user Read safety instructions and SDS before handling. · Hazard identification number (Kemler code): · EMS Number: · Stowage Category · Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code Not applicable. · Transport/Additional information: · DOT · Quantity limitations Not applicable · IMDG · Limited quantities (LQ) Not applicable · Excepted quantities (EQ) Not applicable · · UN “Model Regulation”: UN2586, Alkyl, aryl sulphonic acid, Liquid with not more than 5% free Sulphuric Acid · Sara · Section 355 (extremely hazardous substances): None of the ingredients is listed. · Section 313 (Specific toxic chemical listings): None of the ingredients is listed. · TSCA (Toxic Substances Control Act): None of the ingredients is listed. · Hazardous Air Pollutants None of the ingredients is listed. · Proposition 65 · Chemicals known to cause cancer: None of the ingredients is listed. · Chemicals known to cause reproductive toxicity for females: None of the ingredients is listed. · Chemicals known to cause reproductive toxicity for males: None of the ingredients is listed. · Chemicals known to cause developmental toxicity: None of the ingredients is listed. · Carcinogenic categories · NIOSH-Ca (National Institute for Occupational Safety and Health) None of the ingredients is listed. · GHS label elements The product is classified and labeled according to the Globally Harmonized System (GHS). · Hazard pictograms · Signal word Warning · Hazard statements · May be corrosive to the eyes. · May be corrosive to the skin. · Can cause severe respiratory irritation. · May be harmful if swallowed This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. Department issuing SDS: Environment protection department. Date of preparation / last revision Creation date for SDS: 14/08/2024 Revision 1.0, 27/02/2025: Reviewed SDS for accuracy. STN/GW 16 Other information Precautionary statements · Wear protective gloves / protective clothing / eye protection / face protection. · If swallowed: Call a poison center / doctor if you feel unwell. · If on skin: Wash with plenty of water. Call a poison center / doctor if you feel unwell. · If in eyes: Rinse cautiously with water for several minutes. · Remove contact lenses, if present and easy to do. Continue rinsing. · If exposed or concerned: Call a poison center / doctor · Chemical safety assessment: A Chemical Safety Assessment has not been carried out. *
