Auramine O – Product identifier Trade name: Auramine O 1 Identification 2 Hazard(s) identification · Classification of the substance or mixture Acute Toxicity – H302: Harmful if swallowed. Eye Irritation – H319: Causes serious eye irritation. Carcinogenicity – H351: Suspected of causing cancer. Long term aquatic hazard – H411: Toxic to aquatic life with long lasting effects. · Label elements · GHS label elements The product is classified and labeled according to the Globally Harmonized System (GHS). · Hazard pictograms · Signal word Warning · Hazard statements H302 – Harmful if swallowed. H319 – Causes serious eye irritation. H351 – Suspected of causing cancer. H411 – Very toxic to aquatic life with long lasting effects. · Precautionary statements Obtain special instructions before use. Avoid release to the environment. If swallowed: Call a poison center / doctor if you feel unwell. If on skin: Wash with plenty of water. Call a poison center / doctor if you feel unwell. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If exposed or concerned: Call a poison center / doctor · Classification system: · NFPA ratings (scale 0 – 4) · Other hazards · Results of PBT and vPvB assessment · PBT: Not applicable. · vPvB: Not applicable. 3 Auramine O – Composition/information on ingredients Chemical characterization: Mixtures Description: Mixture of the substances listed below with nonhazardous additions. Description of first aid measures General information: First aiders need to protect themselves. Show this material safety data sheet to the doctor in attendance. After inhalation: Fresh air. Call in physician. After skin contact: Take off immediately all contaminated clothing. Rinse skin with water / shower. Call a physician immediately. After eye contact: Rinse out with plenty of water. Immediately call in ophthalmologist. After swallowing: Immediately make person drink water (two glases at most). Consult a physician. Information for doctor: Most important symptoms and effects, both acute and delayed No further relevant information available. Indication of any immediate medical attention and special treatment needed No further relevant information available. Extinguishing media Suitable extinguishing agents: Water, Foam, Carbon Dioxide (CO2), Dry powder. Special hazards arising from the substance or mixture Carbon oxides, Combustible, Hydrogen chloride gas, Nitrogen oxides. Advice for firefighters: Stay in danger area only with self-contained breathing apparatus. Protective equipment: Mouth respiratory protective device. · Personal precautions, protective equipment and emergency procedures Mount respiratory protective device. Wear protective equipment. Keep unprotected persons away. · Substances: CAS: 2465-27-2 Auramine < = 100% 4 First-aid measures 5 Fire-fighting measures 6 Auramine O – Accidental release measures Environmental precautions: Do not let product enter drains. Methods and material for containment and cleaning up: Cover drains, collect, bind and pump off spills. Observe material restrictions. Avoid generation of dusts. Reference to other sections See Section 7 for information on safe handling. See Section 8 for information on personal protection equipment. See Section 13 for disposal information. Protective Action Criteria for Chemicals 7 Auramine O – Handling and storage Handling: Work under hood. Do not inhale substance/mixture. Precautions for safe handling Ensure good ventilation/exhaustion at the workplace. Open and handle with care. Information about protection against explosions and fires: No data available. Conditions for safe storage, including any incompatibilities Storage: Requirements to be met by storerooms and receptacles: Store in a cool location. Information about storage in one common storage facility: Not required. Further information about storage conditions: Keep receptacle tightly sealed. Store in cool, dry conditions in well sealed receptacles. Specific end use(s) No further relevant information available. 8 Exposure controls/personal protection · Additional information about design of technical systems: No further data; see section 7. · Components with limit values that require monitoring at the workplace: The following constituents are the only constituents of the product which have a PEL, TLV or other recommended exposure limit. At this time, the remaining constituent has no known exposure limits. · Additional information: The lists that were valid during the creation were used as basis. · Exposure controls · Personal protective equipment: · General protective and hygienic measures: Immediately remove all soiled and contaminated clothing. Wash hands before breaks and at the end of work. Store protective clothing separately. Avoid contact with the eyes and skin. · Breathing equipment: In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use respiratory protective device that is independent of circulating air. · Protection of hands: The glove material has to be impermeable and resistant to the product/ the substance/ the preparation. Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the chemical mixture. Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation · Material of gloves The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the application. · Penetration time of glove material The exact break through time has to be found out by the manufacturer of the protective gloves and has to be observed. · Eye protection: · Body protection: Protective work clothing 9 Auramine O – Physical and chemical properties · Information on basic physical and chemical properties · General Information · Appearance: Form: Colored Powder Color: Yellow · Odor: Odorless · Odor threshold: Not determined. · pH-value: 6 – 4 · Change in condition Melting point/Melting range: Boiling point/Boiling range: 265 – 267℃ Not applicable. · Flash point: Not applicable. · Flammability (solid, gaseous): Not applicable. · Molecular Weight: 303.84 · Decomposition temperature: 250 ℃ · Ignition temperature: Not applicable. Reactivity None known. Chemical stability: Stable under standard ambient conditions. Thermal decomposition / conditions to be avoided: No data available. Possibility of hazardous reactions No data available. Conditions to avoid No data available. Incompatible materials: No further relevant information available. Hazardous decomposition products: In the event of fire: see section 5 Information on toxicological effects Acute toxicity: Primary irritant effect: on the skin: No skin irritation. on the eye: Causes eye irritation. Sensitization: No data available. Additional toxicological information: The product shows the following dangers according to internally approved calculation methods for preparations: Irritant to eyes. · Danger of explosion: Not applicable. · Vapor pressure: Not applicable. · Density at 20℃: · Relative density · Vapor density · Evaporation rate Approximately 1.1 g/ml Not determined. Not determined. Not determined. · Solubility in / Miscibility with Water: 10 g/l · Partition coefficient (n-octanol/water): 2.98 · Viscosity: Dynamic: Kinematic: Not determined. Not determined. · Other information No further relevant information available. 10 Stability and reactivity 11 Auramine O – Toxicological information · Carcinogenic categories 14 Auramine O – Transport information · IARC (International Agency for Research on Cancer) Limited evidence of a carcinogenic effect. · NTP (National Toxicology Program) None of the ingredients is listed. · OSHA-Ca (Occupational Safety & Health Administration) None of the ingredients is listed. · UN-Number · DOT, IMDG, IATA 3077 · UN proper shipping name · DOT ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (Auramine) · IMDG, IATA ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (Auramine) Waste treatment methods No data available. Uncleaned packagings: Recommendation: Disposal must be made according to official regulations. Recommended cleansing agent: Water, if necessary with cleansing agents. 13 Disposal considerations Toxicity: No data available. Aquatic toxicity: No further relevant information available. Persistence and degradability No further relevant information available. Behavior in environmental systems: Bio accumulative potential No further relevant information available. Mobility in soil No further relevant information available. Additional ecological information: General notes: Do not allow product to reach drains. Results of PBT and vPvB assessment PBT: Not applicable. vPvB: Not applicable. Other adverse effects No further relevant information available. 12 Auramine O – Ecological information · Safety, health and environmental regulations/legislation specific for the substance or mixture No further relevant information available. 15 Regulatory information · Transport hazard class(es) · DOT OClass 9 · IMDG, IATA .Class 9 · Packing group · DOT, IMDG, IATA III · Environmental hazards: · Marine pollutant: Yes · Special precautions for user Not applicable · Hazard identification number (Kemler code): · EMS Number: · Stowage Category · Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code Not applicable. · Transport/Additional information: · DOT · Quantity limitations On passenger aircraft/rail: 5 L On cargo aircraft only: 60 L · IMDG · Limited quantities (LQ) 1L · Excepted quantities (EQ) Maximum net quantity per inner packaging: 30 ml Maximum net quantity per outer packaging: 500 ml · · UN “Model Regulation”: UN3077, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (Auramine) · Sara · Section 355 (extremely hazardous substances): None of the ingredients is listed. · Section 313 (Specific toxic chemical listings): None of the ingredients is listed. · TSCA (Toxic Substances Control Act): None of the ingredients is listed. · Hazardous Air Pollutants None of the ingredients is listed. · Proposition 65 · Chemicals known to cause reproductive toxicity for females: None of the ingredients is listed. · Chemicals known to cause reproductive toxicity for males: None of the ingredients is listed. · Chemicals known to cause developmental toxicity: None of the ingredients is listed. · Carcinogenic categories · NIOSH-Ca (National Institute for Occupational Safety and Health) None of the ingredients is listed. · GHS label elements The product is classified and labeled according to the Globally Harmonized System (GHS). · Hazard pictograms · Signal word Warning · Hazard statements Harmful if swallowed. Causes serious eye irritation. Suspected of causing cancer. Toxic to aquatic life with long lasting effects. This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. Department issuing SDS: Environment protection department. Date of preparation / last revision Creation date for SDS: 14/08/2024 Revision 1.0, 27/02/2025: Reviewed SDS for accuracy. STN/GW 16 Other information Precautionary statements · Obtain special instructions before use. · Avoid release to the environment. · If swallowed: Call a poison center / doctor if you feel unwell. · If on skin: Wash with plenty of water. Call a poison center / doctor if you feel unwell. · If in eyes: Rinse cautiously with water for several minutes. · Remove contact lenses, if present and easy to do. Continue rinsing. · If exposed or concerned: Call a poison center / doctor · Chemical safety assessment: A Chemical Safety Assessment has not been carried out. *
